One of my favourite SLR features is slow flash sync, where the camera uses a slower shutter speed (longer opening time) than would otherwise be required when using a flash. The flash illuminates and freezes the things nearer to the camera, while the longer shutter opening time allows the camera's sensor to get enough light from things further from the camera that they don't end up too dark in the final photo.
This is not a tutorial, however, it's a tale of woe. I took my current digital SLR (Fujifilm S3 Pro) and my flash (Nikon SB-800) to a family wedding recently, with the hope of taking some nice shots for posterity. The rooms in which the weddings (it was in Germany, where there can be two ceremonies, one civil and one religious) and reception took place were sufficiently large that I wanted to use slow flash sync so that the photos didn't have dark backgrounds. I used to do this a lot with my film SLR (Nikon F-601), and it worked out pretty well most of the time.
Now, the reason you use a flash is because there isn't enough light for a normal photo. If you tried to use the available light, the exposure would take so long that the photo would be blurred (either from the camera shaking slightly in your own hands, or from your subjects moving around). With a slow flash sync, you are relying on the flash freezing the things near the camera so that they aren't blurred. It doesn't matter if the things in the background are a little blurred.
What I didn't notice until later in the evening at the reception was that there was more ambient light that I expected, so the flash wasn't strong enough (in comparison to the ambient light) to freeze the people near the camera. I should have paid more attention to the shutter speed, to make sure that it wasn't too far beyond the maximum for hand-held shots. The rule of thumb is 1/focal-length for 35mm SLRs, e.g. 1/35 of a second for a 35mm lens. For a typical digital camera (with a sensor smaller than 35mm), I expect you should divide that time by a further 1.5 to 2, i.e. 1/50 to 1/70 second in this case. So for a shot with the zoom set at 35mm, I should have checked that the shutter speed wasn't too much greater than 1/50 second (e.g. maybe 1/30).
With the small screen on the back of the camera, I didn't notice the blurring (I should have zoomed in to check it properly, but I didn't, I was too busy taking the next photo). Only later in the evening did I notice, at which point I stopped using slow flash sync, and just used normal flash sync. It's a great pity, because a lot of otherwise nicely composed photos ended up blurred and useless. I took over 300 photos, so I had a lot of examples of my mistake to remind me of what I need to do next time. Don't let it happen to you.
(I haven't posted any examples here, because it wouldn't be fair to post failed photos from somebody's wedding.)
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